This work aims to make a unique polymer to be used as a conductive and flexible chip antenna. Its properties are robustness, rigidity, stretchability, and good conduction. The fabricated composite is composed of two copolymers, Polydimethylsiloxane (PDMS) and Polyethylenimine (PEI), assembled with nano metals (Copper, Silver), and graphene nanoparticles as a matrix. Nano metals fill out the inter-layer space, and polymer voids reinforce the cross linker. Graphene/metal nanoparticles help make chelating complexes using metallic bonds, enhancing the polymer’s conductivity from 1.87 × 10-4 to 5.64 ×10-6 σ Scm-1. The conductivity, self-healing, and surface morphology of fabricated composite are analyzed using different spectroscopic techniques, such as electrochemical impedance (EIS), Scanning Electronic Microscopy (SEM), Transition Electronic Microscopy (TEM), Infrared spectroscopy (IR), UV-Visible spectroscopy (UV), and a particle size analyzer.

Two heterocyclic oximes (E)-N-hydroxy-1-(pyridin-2-yl)methanimine (Hp2ylm) and (E)-N-hydroxy-1-(pyridin-3-yl)methanimine (Hp3ylm) were synthesized from pyridine-2-carbaldehyde and pyridine-3-carbaldehyde, respectively. These oximes were characterized by various spectroscopic tools like UV, IR, MASS and NMR. The inhibition capacity of these oximes against copper corrosion in 0.1 M HNO3 was determined by polarization and impedance spectroscopic studies (EIS). At all concentrations, Hp3ylm exhibited higher inhibition efficiency than Hp2ylm. Attempt was made to illustrate the mechanism of corrosion inhibition by these oximes with the help of adsorption isotherm, scanning electron microscopic (SEM) and quantum chemical studies.

The adsorption behavior of a potential polynuclear Schiff base, (s)-2-(anthracen-9(10H)-ylideneamino)-3-phenyl propanoic acid (A9Y3PPA) on carbon steel (CS) in 1M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization studies. The surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by AFM analysis. The corrosion inhibition efficiencies of parent amine and parent ketone on carbon steel in 1M HCl solution have also been investigated using weight loss studies. The adsorption of A9Y3PPA obeys Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ∆G0ads) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ∆H* and ∆S*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y3PPA acts as a mixed type inhibitor. A probable inhibition mechanism was also proposed.